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Ligand displacement reactions from the coordination sphere of cobalt complexes. Part II: The displacement of ligands of [cis-Co(en)2Cl2]Cl by potassium squarate. The crystal and molecular structure of a compound with idealized formula of [cis-Co(en)2(H2O)Br]2[trans-(C2O42−(C2O4H−)Co-trans-(H2O)2(OH)2]Br2(I)

✍ Scribed by Jiwen Cai; Ivan Bernal; Frank Fronczek; Steven F. Watkins


Publisher
Springer
Year
1996
Tongue
English
Weight
539 KB
Volume
7
Category
Article
ISSN
1040-0400

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.