A generalization is given of the cell method for the liquid state, by taking into account in a systematic way the collective motion of more than one molecule in cell-clusters of more than one cell. A rigourous expression is derived for the partition function in terms of cell-cluster integrals over c
Cell theory for the liquid state
β Scribed by Adams, D. J.; Matheson, A. J.
- Book ID
- 121449972
- Publisher
- The Royal Society of Chemistry
- Year
- 1972
- Weight
- 629 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0300-9238
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π SIMILAR VOLUMES
The cell-cluster theory for the liquid state developed in a previous paper ') has been completed by evaluating the combinatorial factor which is involved. In the 1-dimensional case this combinatorial factor can be given in exact form. In the 2-and 3dimensional case approximate solutions are obtained
In this paper the cell-cluster theory for the liquid state developed in two previous papers 1) 3) is applied to the case that the total intermolecular potential field can be approximated by a harmonic potential field. This model can be applied to the solid state as well as to the liquid state and g