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Cell-cluster theory for the liquid state I

✍ Scribed by J. De Boer

Publisher: Elsevier Science
Year: 1954
Weight: 499 KB
Volume: 20
Category: Article
ISSN: 0031-8914
DOI: 10.1016/s0031-8914(54)80077-2

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✦ Synopsis

A generalization is given of the cell method for the liquid state, by taking into account in a systematic way the collective motion of more than one molecule in cell-clusters of more than one cell. A rigourous expression is derived for the partition function in terms of cell-cluster integrals over clusters of two, three, etc. cells, but for the evaluation of the corresponding complicated combinatorial problem approximative methods have to be used. The applications will be given in subsequent publications~

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