✦ LIBER ✦

A cell-cluster theory for the liquid state. II

✍ Scribed by E.G.D. Cohen; J. De Boer; Z.W. Salsburg

Publisher: Elsevier Science
Year: 1954
Weight: 513 KB
Volume: 21
Category: Article
ISSN: 0031-8914
DOI: 10.1016/s0031-8914(54)91026-5

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✦ Synopsis

The cell-cluster theory for the liquid state developed in a previous paper ') has been completed by evaluating the combinatorial factor which is involved. In the 1-dimensional case this combinatorial factor can be given in exact form. In the 2-and 3dimensional case approximate solutions are obtained for this combinatorial problem, using a method similar to that introduced by K i k u c h i. As an example the formulae are applied to the ideal gas case. This leads to a complete appearance of the "communal entropy" in the 1-dimensional case. In the 2-and 3-dimensional cases the first correction accounts already for a large part of this "communal entropy".

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