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Cationic (η 6 -Arene)tricarbonylmanganese Linked to Neutral (η 6 -Arene)tricarbonylchromium Complexes

✍ Scribed by Schouteeten, Stéphanie; Tranchier, Jean-Philippe; Rose-Munch, Françoise; Rose, Eric; Auffrant, Audrey; Stephenson, G. Richard

Book ID
127211476
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
189 KB
Volume
23
Category
Article
ISSN
0276-7333

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(η6-Arene)tricarbonylchromium and (η5-cy
(η6-Arene)tricarbonylchromium and (η5-cyclohexadienyl) tricarbonylmanganese complexes: indirect nucleophilic substitutions
✍ Françoise Rose-Munch; Vanessa Gagliardini; Christophe Renard; Eric Rose 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 528 KB

Treatment of X-substituted (g6-arene)tricarbonylchromium complexes with a nucleophile and a proton source afforded new arenetricarbonylchromium complexes via chromium hydride intermediates and elimination of HX (cine and tele nucleophilic aromatic substitutions). Treatment of (g5-X-substituted-cyclo