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(η6-arene) tricarbonylchromium complex in organic synthesis: stereoselective alkylation at benzylic position of (η6-Arene) tricarbonylchromium

✍ Scribed by Motokazu Uemura; Kazuo Isobe; Yuji Hayashi

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
208 KB
Volume
26
Category
Article
ISSN
0040-4039

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Addition of a nucleophile to an (η 6 -arene)tricarbonylchromium or a tricarbonyl(η 5 -cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves

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