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Cationic polymerization of styrene by means of pulse radiolysis

✍ Scribed by S. Egusa; S. Arai; A. Kira; M. Imamura; Y. Tabata

Publisher
Elsevier Science
Year
1977
Weight
457 KB
Volume
9
Category
Article
ISSN
0146-5724

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Electroinitiated cationic polymerization
Electroinitiated cationic polymerization of styrene
✍ Funt, B. L. ;Blain, T. J. πŸ“‚ Article πŸ“… 1970 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 477 KB

## Abstract A constant controlled current was passed through a solution of styrene in methylene chloride containing a tetraalkylammonium salt as supporting electrolyte. Reproducible rates of polymerization were initiated by the electrochemical techniques employed and the kinetics of the reaction we

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Cationic polymerization of styrene(St) initiated by phosphorus trichloride(PC13) in nitrobenzene was carried out at 30 Β°. The initial rate was proportional to [St] 2 and [PCl3]. The overall activation energy was about 10.4 kcal/mole. The rate and the degree of polymerization were enhanced with incre