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Cationic .pi.-allylic palladium complexes with the additional intramolecular olefin coordination

✍ Scribed by Takahashi, Yasutaka.; Sakai, Shizuyoshi.; Ishii, Yoshio.


Book ID
127312325
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
456 KB
Volume
11
Category
Article
ISSN
0020-1669

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The oxidative addition of the allylic acetate, CH 2 CH Γ€ CH 2 Γ€ OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h