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The reactions of tridentate cationic palladium(II) complexes with olefins and nucleophiles

✍ Scribed by Heinz-Bernhard Kraatz; David Milstein

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 886 KB
Volume: 488
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(94)00027-a

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## Abstract The migratory insertions of __cis__ or __trans__ olefins CH(X)CH(Me) (X = Ph, Br, or Et) into the metal–acyl bond of the complex [Pd(Me)(CO)(^i^Pr~2~dab)]^+^ [B{3,5‐(CF~3~)~2~C~6~H~3~}~4~]^−^ (1) (^i^Pr~2~dab = 1,4‐diisopropyl‐1,4‐diazabuta‐1,3‐diene = __N,N′__‐(ethane‐1,2‐diylidene)bi