Cationic Intermediates in the Intramolecular Insertion of Alkenes into (η3-Allyl)palladium(II) Complexes

Rate and Mechanism of the Reversible For

Rate and Mechanism of the Reversible Formation of Cationic (η3-Allyl)- palladium Complexes in the Oxidative Addition of Allylic Acetate to Palladium(0) Complexes Ligated by Diphosphanes

✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h