Cationic Mn 4 Single-Molecule Magnet with a Sterically Isolated Core
✍ Scribed by Heroux, Katie J.; Quddusi, Hajrah M.; Liu, Junjie; O’Brien, James R.; Nakano, Motohiro; del Barco, Enrique; Hill, Stephen; Hendrickson, David N.
- Book ID
- 118017802
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 732 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
The salicylamidoxime-based complex [Mn 6 (μ 3 -O) 2 (H 2 N-sao) 6 (py) 6 -(EtOH) 2 ](ClO 4 ) 2 •4EtOH (1•4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn III 6 ] single-molecule magnets.
## Abstract The reaction of [Mn~6~O~2~(Piv)~10~(4‐Me‐py)~2.5~(PivH)~1.5~] (1) (py: pyridine, Piv: pivilate) with __N__‐methyldiethanolamine (mdeaH~2~) and Ln(NO~3~)~3~⋅6 H~2~O in MeCN leads to a series of nonanuclear compounds [Mn~5~Ln~4~(O)~6~(mdea)~2~(mdeaH)~2~(Piv)~6~(NO~3~)~4~(H~2~O)~2~]⋅2 MeCN