A cationic and ferromagnetic hexametallic Mn(iii) single-molecule magnet based on the salicylamidoxime ligand

✍ Scribed by Martínez-Lillo, José; Dolan, Neil; Brechin, Euan K.

• Book ID: 120586628
• Publisher: Royal Society of Chemistry
• Year: 2013
• Tongue: English
• Weight: 688 KB
• Volume: 42
• Category: Article
• ISSN: 1477-9226
• DOI: 10.1039/C3DT51512E

✦ Synopsis

The salicylamidoxime-based complex [Mn 6 (μ 3 -O) 2 (H 2 N-sao) 6 (py) 6 -(EtOH) 2 ](ClO 4 ) 2 •4EtOH (1•4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn III 6 ] single-molecule magnets.