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A cationic and ferromagnetic hexametallic Mn(iii) single-molecule magnet based on the salicylamidoxime ligand

✍ Scribed by Martínez-Lillo, José; Dolan, Neil; Brechin, Euan K.

Book ID
120586627
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
688 KB
Volume
42
Category
Article
ISSN
1477-9226

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A cationic and ferromagnetic hexametalli
A cationic and ferromagnetic hexametallic Mn(iii) single-molecule magnet based on the salicylamidoxime ligand
✍ Martínez-Lillo, José; Dolan, Neil; Brechin, Euan K. 📂 Article 📅 2013 🏛 Royal Society of Chemistry 🌐 English ⚖ 688 KB

The salicylamidoxime-based complex [Mn 6 (μ 3 -O) 2 (H 2 N-sao) 6 (py) 6 -(EtOH) 2 ](ClO 4 ) 2 •4EtOH (1•4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn III 6 ] single-molecule magnets.