Cationic Catalyzed Polymerization of Styrene at High Conversion
β Scribed by Endres, G. F.; Kamath, V. G.; Overberger, C. G.
- Book ID
- 127203322
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 640 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract A constant controlled current was passed through a solution of styrene in methylene chloride containing a tetraalkylammonium salt as supporting electrolyte. Reproducible rates of polymerization were initiated by the electrochemical techniques employed and the kinetics of the reaction we
An experimental study of thermal polymerization of styrene in the temperature range 100-20O0C and conversion range 0-100% is reported. Conversions, molecular weight averages, and molecular weight distributions were measured. A kinetic model with third-order initiation gives a satisfactory fit of con