Living cationic polymerization of styrene was achieved with a series of initiating systems consisting of a HX-styrenic monomer adduct (X ΒΌ Br, Cl) and ferric chloride (FeCl 3 ) in conjunction with added salts such as tetrabutylammonium halides ) and in toluene. Comparison of the molecular weight di
β¦ LIBER β¦
Cationic polymerization of vinyl monomers with latent catalysts. I. Cationic polymerization of styrene with a benzylsulfonium salt at high temperature
β Scribed by Takeshi Endo; Atsushi Kikkawa; Hitomi Uno; Hiroyuki Sato; Misao Hiza; Toshikazu Takata
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1989
- Tongue
- English
- Weight
- 225 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0887-6258
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## Abstract New initiating systems for the thermal cationic polymerization of epoxides and vinyl ether derivatives are proposed. They are based on a silane/silver salt interaction, which ensures a good to excellent polymerization at room temperature. Moreover, the polymerization is much more effici