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Cation radicals. XXVIII. Isolation and some reactions of dibenzodioxin cation radical perchlorate

โœ Scribed by Henry J. Shine; Lewis R. Shade

Book ID
112123134
Publisher
Journal of Heterocyclic Chemistry
Year
1974
Tongue
English
Weight
279 KB
Volume
11
Category
Article
ISSN
0022-152X

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๐Ÿ“œ SIMILAR VOLUMES

Ion radicals. XXXI. Reaction of thianthr
Ion radicals. XXXI. Reaction of thianthrene cation radical perchlorate with ketones. Formation of ฮฒ-ketoalkylsulfonium perchlorates and ylides
โœ Kyongtae Kim; Henry J. Shine ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 175 KB

B-Ketoalkylsulfonium salts are ordinarily made by reaction of an o-halogenoketone with an organic sulfide. Phenacyl bromide is often used (eq. 1); a-bromoesters (=.a., methyl bromoacetate) are also used. 2 This method is quite old, having been used, for example, by Clarke