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Reaction of thianthrene cation radical with alcohols: Isolation and chemistry of 5-cyclohexyloxythianthreniumyl perchlorate

โœ Scribed by Wenyi Zhao; Henry J. Shine

Book ID
103408898
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
126 KB
Volume
37
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Ion radicals. XXXI. Reaction of thianthr
Ion radicals. XXXI. Reaction of thianthrene cation radical perchlorate with ketones. Formation of ฮฒ-ketoalkylsulfonium perchlorates and ylides
โœ Kyongtae Kim; Henry J. Shine ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 175 KB

B-Ketoalkylsulfonium salts are ordinarily made by reaction of an o-halogenoketone with an organic sulfide. Phenacyl bromide is often used (eq. 1); a-bromoesters (=.a., methyl bromoacetate) are also used. 2 This method is quite old, having been used, for example, by Clarke