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Ion radicals. 39. Reactions of 10-methyl- and 10-phenylphenothiazine cation radical perchlorates with ketones

โœ Scribed by Padilla, A. Gregory; Bandlish, Baldev K.; Shine, Henry J.


Book ID
126324191
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
528 KB
Volume
42
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


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B-Ketoalkylsulfonium salts are ordinarily made by reaction of an o-halogenoketone with an organic sulfide. Phenacyl bromide is often used (eq. 1); a-bromoesters (=.a., methyl bromoacetate) are also used. 2 This method is quite old, having been used, for example, by Clarke

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Reaction of (a) superoxide and (b) ozonate radical-ions with the title dichloride does not give the corresponding endo-peroxide and ozonide,respectively. A variety of products formed by nucleophilic substitution and reductive dehalogenation were isolated.