Ion radicals. 39. Reactions of 10-methyl- and 10-phenylphenothiazine cation radical perchlorates with ketones
โ Scribed by Padilla, A. Gregory; Bandlish, Baldev K.; Shine, Henry J.
- Book ID
- 126324191
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 528 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
B-Ketoalkylsulfonium salts are ordinarily made by reaction of an o-halogenoketone with an organic sulfide. Phenacyl bromide is often used (eq. 1); a-bromoesters (=.a., methyl bromoacetate) are also used. 2 This method is quite old, having been used, for example, by Clarke
Reaction of (a) superoxide and (b) ozonate radical-ions with the title dichloride does not give the corresponding endo-peroxide and ozonide,respectively. A variety of products formed by nucleophilic substitution and reductive dehalogenation were isolated.