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catena-Poly[tris(ethyl­enediamine-κ2N,N′)nickel(II) [cadmium(II)-di-μ-1,2-dicyano­ethyl­enedithiol­ato-κ3S,S′:S′] monohydrate]

✍ Scribed by Fu, Ai-Yun ;Wang, Da-Qi ;Xing, Jian-Xin

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
330 KB
Volume
61
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

catena-Poly[[[diaqua­cadmium(II)]-di-μ-1
catena-Poly[[[diaqua­cadmium(II)]-di-μ-1-amino-2,2-dicyano­ethene-1-thiol­ato-κ2S:N;κ2N:S] dihydrate]
✍ Zhang, Shi-Guo ;Xu, Hong-Kun ;Shi, Jing-Min ;Liu, Lian-Dong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 119 KB

The title compound, {[Cd(C 4 H 2 N 3 S) 2 (H 2 O) 2 ]Á2H 2 O} n , forms a one-dimensional chain propagating along the a axis. The unique Cd II atom lies on an inversion centre in a slightly distorted octahedral coordination environment. In the crystal structure, a three-dimensional network is formed

Tris­(ethyl­enedi­amine-κ2N,N′)­cadmium(
Tris­(ethyl­enedi­amine-κ2N,N′)­cadmium(II) bis­(1,2-dicyanoethylenedithiolato-κ2S,S′)­cuprate(II)
✍ Wang, Da-Qi ;Fu, Ai-Yun ;Wei, Xi-Lian 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 215 KB

In the title complex, [Cd(C 2 H 8 N 2 ) 3 ][Cu(C 4 N 2 S 2 ) 2 ], the Cd II atom has a distorted octahedral geometry. The Cu II atom is in a distorted square-planar geometry. Both ions lie on twofold rotation axes. They are not connected covalently.