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catena-Poly[[[diaqua­cadmium(II)]-di-μ-1-amino-2,2-dicyano­ethene-1-thiol­ato-κ2S:N;κ2N:S] dihydrate]

✍ Scribed by Zhang, Shi-Guo ;Xu, Hong-Kun ;Shi, Jing-Min ;Liu, Lian-Dong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
119 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, {[Cd(C 4 H 2 N 3 S) 2 (H 2 O) 2 ]Á2H 2 O} n , forms a one-dimensional chain propagating along the a axis. The unique Cd II atom lies on an inversion centre in a slightly distorted octahedral coordination environment. In the crystal structure, a three-dimensional network is formed via intermolecular O-

📜 SIMILAR VOLUMES

catena-Poly[[diaqua­(1,10-phenanthroline
catena-Poly[[diaqua­(1,10-phenanthroline-κ2N,N′)cadmium(II)]-μ-fumarato-κ2O:O′]
✍ Sun, Ya-Guang ;Gao, En-Jun ;Liu, Xia ;Wang, Cheng-Chen 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 276 KB

In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h