The title compound, [Sn~2~Cl~2~(CH~3~)~4~(C~6~H~5~N~2~O~2~)~2~], forms infinite one-dimensional zigzag chains that propagate in a helical fashion along the __c__ axis __via__ an Sn—O=C—O—Sn—O bridge which involves the carboxylate groups of two methylpyrazinecarboxylate ligands. These display both ch
catena-Poly[[triphenyltin(IV)]-μ-6-oxo1,6-dihydropyridine-3-carboxylato]
✍ Scribed by Gao, Zhong-Jun ;Yin, Han-Dong ;Li, Gang ;Wang, Da-Qi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 168 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, [Sn(C~6~H~5~)~3~(C~6~H~4~NO~3~)], possesses an infinite chain structure. The SnO~2~C~3~ centre has distorted trigonal–bipyramidal geometry with the O atoms in the apical positions. A strong intermolecular N—H...O hydrogen bond results in the formation of double chains.
📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, [Sn(C 4 H 9 ) 3 -(C 6 H 4 NO 2 )] n , consists of three butyl and one pyridine-3carboxylate groups bonded to the Sn atom in a distorted trigonal-bipyramidal geometry. In the crystal structure, these units are linked to form an infinite one-dimensional polym
The crystal structure determination of the title compound, [Sn(C~4~H~9~)~2~(C~8~F~4~O~4~)]~__n__~, revealed an infinite polymeric chain in the solid state. The Sn atom is in a distorted sixfold coordination between bicapped tetrahedral and skew-bipyramidal.
catena-Poly [[[diaqua(6-