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catena-Poly[[silver(I)-μ-1,2-di­amino­ethane] hexa­fluoro­arsenate]

✍ Scribed by Zhu, Hai-Liang ;Sun, Zhi-Yuan ;Rong, Na-Na ;Zhang, Biao ;Zhang, Min ;Li, Yong


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
212 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê R factor = 0.048 wR factor = 0.135 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Bis(2-amino­pyridine-κN1)silver(I) hexa­
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.037 wR factor = 0.098 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, {[Ag(bpe)](OTf)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the