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catena-Poly­[[silver(I)-μ-1,4-di­amino­butane-κ2N:N′] hexa­fluoro­arsenate]

✍ Scribed by Zhu, Hai-Liang ;Ma, Ji-Long ;Qiu, Xiao-Yang ;Shao, Si-Chang ;Yang, Song ;Sun, Lin


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
466 KB
Volume
59
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê R factor = 0.048 wR factor = 0.135 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.037 wR factor = 0.098 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, [Ag(C~4~H~4~N~2~)]ClO~4~, pyrazine ligands bridge two symmetry-related Ag atoms [Ag—N = 2.222 (3) Å] to form linear polycationic chains which run along the __c__ axis of the orthorhombic unit cell. The Ag^I^ ion has __m__2__m__ site symmetry. The N atoms of the pyrazine ligand