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catena-Poly[[(diethyl ether-κO)lithium(I)]-μ-1,1,3,3-tetra­isopropyl­triphosphane-κP2:κ2P1,P3-lithium(I)-μ-1,1,3,3-tetra­isopropyl­triphosphane-κ2P1,P3:κP2]

✍ Scribed by Domanska, Wioleta ;Chojnacki, Jaroslaw ;Pikies, Jerzy

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
214 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Li 2 (C 12 H 28 P 3 ) 2 (C 4 H 10 O)] n , is a byproduct of the reaction of [(Et 2 PhP) 2 PtCl 2 ] with i Pr 2 P-P(SiMe 3 )Li in tetrahydrofuran. It is the second coordination polymer among known triphosphane-lithium salts. Of the two independent Li atoms, one is tetrahedrally coordinated, whereas the second has a trigonal environment.

📜 SIMILAR VOLUMES

Bis[μ2-bis(diphenylphosphino)methane]-1:
Bis[μ2-bis(diphenylphosphino)methane]-1:2κ2P:P′;2:3κ2P:P′-dichlorido-1κCl,3κCl-triangulo-trigold(I) hexafluorophosphate
✍ Constable, Edwin C. ;Housecroft, Catherine E. ;Neuburger, Markus ;Schaffner, Sil 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 759 KB

## Data collection Nonius KappaCCD diffractometer Absorption correction: multi-scan DENZO and SCALEPACK (Otwinowski & Minor, 1997) T min = 0.38, T max = 0.45 23737 measured reflections 12197 independent reflections 8452 reflections with I > 3(I) R int = 0.026 Refinement R[F 2 > 2(F 2 )] = 0.036 wR