𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[cyclo­hexyl­ammonium [cadmate(II)-tri-μ-bromido]]

✍ Scribed by Rademeyer, Melanie

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
336 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, {(C~6~H~14~N)[CdBr~3~]}~n~, self-assembles into a layered structure consisting of alternating organic and inorganic layers, with the two Cd atoms on inversion centres. In the inorganic layer, octahedral CdBr~6~ units share faces to form a one-dimensional perhalometallate chain, which interacts with the ammonium groups of the cations through hydrogen bonds, forming a two-dimensional hydrogen-bonded sheet.

📜 SIMILAR VOLUMES

catena-Poly[benzyl­triethyl­ammonium [tr
catena-Poly[benzyl­triethyl­ammonium [tri-μ-thio­cyanato-κ4N:S;κ2S:N-cadmate(II)]]
✍ Russo, Luca ;Sharma, Raj Pal ;Sharma, Subhranshu ;Sharma, Rajni ;Rissanen, Kari 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 321 KB

The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit c

catena-Poly[benzyl­trimethyl­ammonium [c
catena-Poly[benzyl­trimethyl­ammonium [cadmium(II)-tri-μ2-thio­cyanato]]
✍ Bala, Ritu ;Kennedy, Alan R. ;Saneja, Kalpna ;Sharma, Raj Pal 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 229 KB

The title compound, {(C~10~H~16~N)[Cd(SCN)~3~]}~__n__~, contains [(C~6~H~5~CH~2~)N(CH~3~)~3~]^+^ cations lying between one-dimensional chains of stoichiometry {[Cd(SCN)~3~]^−^}~__n__~. Each Cd^II^ ion is 3__N__,3__S__-hexacoordinated by thiocyanate ligands, in an octahedral __fac__ arrangement. The

catena-Poly[tetramethylammonium [argenta
catena-Poly[tetramethylammonium [argentate(I)-di-μ-bromido]]
✍ Liu, Xi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 890 KB

The title compound, {(C 4 H 12 N)[AgBr 2 ]} n , is isomorphous with its chloride analogue [Helgesson, Josefsson & Jagner (1988).

catena-Poly[[dichloro­zinc(II)]-μ-cyano­
catena-Poly[[dichloro­zinc(II)]-μ-cyano­guanidine]
✍ Ritche, Lyndsey K. ;Harrison, William T. A. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

The one-dimensional title compound, [ZnCl 2 (C 2 H 4 N 4 )] n , contains ZnCl 2 N 2 tetraheda linked by N,N-bridging cyanoguanidine molecules. A network of N-HÁ Á ÁCl hydrogen bonds help to establish the crystal packing.