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catena-Poly[[[aquasilver(I)]-μ-2,3-dimethylpyrazine-κ2N:N′] 4-amino-2,5-dichlorobenzenesulfonate]

✍ Scribed by Liu, Hai-Yan ;Ma, Ji-Cheng ;Yang, Jin

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
543 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, {Ag(C~6~H~8~N~2~)(H~2~O)}~n~, the Ag^I^ ion is three-coordinated by two N atoms from two symmetry-related 2,3-dimethylpyrazine (dmp) ligands, and one water O atom in a distorted trigonal–planar geometry. The dmp ligands bridge Ag^I^ ions to form a one-dimensional chain structure with charge-balancing 4-amino-2,5-dichlorobenzenesulfonate anions. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds form a two-dimensional network.

📜 SIMILAR VOLUMES

catena-Poly[[(2-amino-5-chlorobenzenesul
catena-Poly[[(2-amino-5-chlorobenzenesulfonato-κ2N,O)silver(I)]-μ-2,5-dimethylpyrazine-κ2N:N′]
✍ Liu, Hai-Yan ;Ma, Ji-Cheng ;Yang, Jin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 405 KB

The title compound, [Ag(C~6~H~5~ClNO~3~S)(C~6~H~8~N~2~)]~__n__~, has a chain structure, where the Ag^I^ cation is four-coordinated by three N atoms from two different 2,5-dimethylpyrazine molecules and an NH~2~ group of a 2-amino-5-chlorobenzenesulfonate anion, and one sulfonate O atom. N—H...O hydr

(2-Amino-4,5-dimethylbenzenesulfonato-κN
(2-Amino-4,5-dimethylbenzenesulfonato-κN)aquasilver(I) monohydrate
✍ Li, Yu-Jie ;Li, Shi-Hua ;Dong, Xian-Wu 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 715 KB

The title compound, [Ag(C~8~H~10~NO~3~S)(H~2~O)]·H~2~O, has a mononuclear structure in which the Ag^+^ cation is two-coordinated by one N atom from a 2-amino-4,5-dimethylbenzenesulfonate anion and one water O atom in a nearly linear arrangement. A network of O—H...O and N—H...O hydrogen bonds helps