𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[[(2-amino-5-chlorobenzenesulfonato-κ2N,O)silver(I)]-μ-2,5-dimethylpyrazine-κ2N:N′]

✍ Scribed by Liu, Hai-Yan ;Ma, Ji-Cheng ;Yang, Jin

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
405 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Ag(C~6~H~5~ClNO~3~S)(C~6~H~8~N~2~)]~n~, has a chain structure, where the Ag^I^ cation is four-coordinated by three N atoms from two different 2,5-dimethylpyrazine molecules and an NH~2~ group of a 2-amino-5-chlorobenzenesulfonate anion, and one sulfonate O atom. N—H...O hydrogen bonds stabilize the structure.

📜 SIMILAR VOLUMES

catena-Poly[[[aquasilver(I)]-μ-2,3-dimet
catena-Poly[[[aquasilver(I)]-μ-2,3-dimethylpyrazine-κ2N:N′] 4-amino-2,5-dichlorobenzenesulfonate]
✍ Liu, Hai-Yan ;Ma, Ji-Cheng ;Yang, Jin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 543 KB

In the title compound, {[Ag(C~6~H~8~N~2~)(H~2~O)](C~6~H~4~Cl~2~NO~3~S)}~__n__~, the Ag^I^ ion is three-coordinated by two N atoms from two symmetry-related 2,3-dimethylpyrazine (dmp) ligands, and one water O atom in a distorted trigonal–planar geometry. The dmp ligands bridge Ag^I^ ions to form a on

catena-Poly­[silver(I)-μ-isonicotinato-κ
catena-Poly­[silver(I)-μ-isonicotinato-κ2O:N]
✍ Yang, Yang-Yi ;Huang, Zhong-Qi ;Ouyang, Gang-Feng ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 159 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.012 A Ê R factor = 0.058 wR factor = 0.155 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

catena-Poly[[(6-aminonaphthalene-1-sulfo
catena-Poly[[(6-aminonaphthalene-1-sulfonato-κO)silver(I)]-μ-2,3,5,6-tetramethylpyrazine-κ2N:N′]
✍ Liu, Hai-Yan ;Ma, Ji-Cheng ;Liu, Ying-Ying 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 779 KB

In the title compound, [Ag(C 10 H 8 NO 3 S)(C 8 H 12 N 2 )] n , the Ag + cation is three-coordinated by two N atoms from two 2,3,5,6tetramethylpyrazine ligands and one O atom from a 7aminonaphthalene-1-sulfonate anion. The 2,3,5,6-tetramethylpyrazine ligand acts as a bridging bidentate ligand, linki

catena-Poly[[silver(I)-μ-pyrazine-κ2N:N′
catena-Poly[[silver(I)-μ-pyrazine-κ2N:N′] perchlorate]
✍ Song, Wen-Dong ;Gu, Chang-Sheng ;Yan, Jian-Bin ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 640 KB

In the title compound, [Ag(C~4~H~4~N~2~)]ClO~4~, pyrazine ligands bridge two symmetry-related Ag atoms [Ag—N = 2.222 (3) Å] to form linear polycationic chains which run along the __c__ axis of the orthorhombic unit cell. The Ag^I^ ion has __m__2__m__ site symmetry. The N atoms of the pyrazine ligand