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catena-Poly[[(6-aminonaphthalene-1-sulfonato-κO)silver(I)]-μ-2,3,5,6-tetramethylpyrazine-κ2N:N′]

✍ Scribed by Liu, Hai-Yan ;Ma, Ji-Cheng ;Liu, Ying-Ying

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
779 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ag(C 10 H 8 NO 3 S)(C 8 H 12 N 2 )] n , the Ag + cation is three-coordinated by two N atoms from two 2,3,5,6tetramethylpyrazine ligands and one O atom from a 7aminonaphthalene-1-sulfonate anion. The 2,3,5,6-tetramethylpyrazine ligand acts as a bridging bidentate ligand, linking the Ag I centres into a one-dimensional chain. The chains are interconnected via intermolecular N-HÁ Á ÁO hydrogen bonds and C-HÁ Á Á interactions, resulting in the formation of a three-dimensional framework.

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(6-Aminonaphthalene-1-sulfonato-κO)bis(3
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The title compound, [Ag(C 10 H 8 NO 3 S)(C 10 H 9 N) 2 ], has a mononuclear structure in which the Ag + cation is threecoordinated by two N atoms from two different 3-methylisoquinoline molecules and one O atom from a 6-aminonaphthalene-1-sulfonate anion in a distorted trigonal-planar AgN 2 O arrang

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The title compound, [Ag(C~6~H~5~ClNO~3~S)(C~6~H~8~N~2~)]~__n__~, has a chain structure, where the Ag^I^ cation is four-coordinated by three N atoms from two different 2,5-dimethylpyrazine molecules and an NH~2~ group of a 2-amino-5-chlorobenzenesulfonate anion, and one sulfonate O atom. N—H...O hydr