(6-Aminonaphthalene-1-sulfonato-κO)bis(3-methylisoquinoline-κN)silver(I)

✍ Scribed by Wang, Xiu-Yan ;Ma, Chao-Hong ;Gao, Qian-Qian ;Lu, Shu-Qin ;Dong, Xian-Wu

• Publisher: International Union of Crystallography
• Year: 2007
• Tongue: English
• Weight: 717 KB
• Volume: 63
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536807039955

✦ Synopsis

The title compound, [Ag(C 10 H 8 NO 3 S)(C 10 H 9 N) 2 ], has a mononuclear structure in which the Ag + cation is threecoordinated by two N atoms from two different 3-methylisoquinoline molecules and one O atom from a 6-aminonaphthalene-1-sulfonate anion in a distorted trigonal-planar AgN 2 O arrangement. A network of N-HÁ Á ÁO hydrogen bonds consolidates the structure.

Related literature

For the related compound, Ag(L1)(3-iso) (L1 = 2-amino-3,5dimethylbenzenesulfonate, 3-iso = 3-methylisoquinoline), containing a trigonal-planar AgN 3 arrangement, see: Li et al. (2007).

Experimental Crystal data [Ag(C 10 H 8 NO 3 S)(C 10 H 9 N) 2 ] M r = 616.47 Triclinic, P1 a = 9.8810 (14) A b = 10.2220 (17) A c = 13.256 (2) A = 80.108 (11) = 86.653 (11) = 84.143 (10) V = 1311.0 (4) A ˚3 Z = 2 Mo K radiation = 0.89 mm À1 T = 292 (2) K 0.35 Â 0.33 Â 0.29 mm Data collection Bruker SMART APEX CCD diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.709, T max = 0.766 8844 measured reflections 5933 independent reflections 2404 reflections with I > 2(I) R int = 0.064 Refinement R[F 2 > 2(F 2 )] = 0.048 wR(F 2 ) = 0.074 S = 0.76 5933 reflections 351 parameters 3 restraints H atoms treated by a mixture of independent and constrained refinement Á max = 0.38 e A ˚À3 Á min = À0.35 e A ˚À3