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catena-Poly[[(18-crown-6)potassium(I)]-μ-chlorido-silver(I)-μ-chlorido]

✍ Scribed by Song, Xing-Min ;Huang, Xian-Qiang ;Dou, Jian-Min ;Li, Da-Cheng


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
1000 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title complex, [AgKCl 2 (C 12 H 24 O 6 )] n , has been synthesized by reaction of 18-crown-6 with KCl and AgNO 3 . [K(18crown-6)] + cations and [AgCl 2 ] À anions form one-dimensional chains through KÁ Á ÁCl interactions of length 3.2568 (14) A ˚. Both the K + and the Ag I ions lie on centres of inversion.


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