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Catecholato complexes of ruthenium, iridium, rhenium, molybdenum, and tungsten

✍ Scribed by Griffith, William P.; Pumphrey, Carol A.; Rainey, Tracey-Anne

Book ID
121427718
Publisher
The Royal Society of Chemistry
Year
1986
Tongue
English
Weight
530 KB
Volume
6
Category
Article
ISSN
1472-7773

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The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound