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Oxo and Nitrido Complexes of Molybdenum, Tungsten, Rhenium, and Osmium. A Theoretical Study

✍ Scribed by Neuhaus, Arndt; Veldkamp, Achim; Frenking, Gernot


Book ID
126424674
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
934 KB
Volume
33
Category
Article
ISSN
0020-1669

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The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound