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Catalytic oxidation of 1-hexene with molecular oxygen by iridium nitro complexes

โœ Scribed by Quijije, L. A. ;Mediavilla, M. ;Pardey, A. J. ;de Pardey, C. Longo ;Baricelli, P. ;Moya, S. A.


Publisher
Springer
Year
1997
Tongue
English
Weight
278 KB
Volume
62
Category
Article
ISSN
0133-1736

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Catalytic oxidation of 1-hexene and cycl
โœ P.J Baricelli; V.J Sรกnchez; A.J Pardey; S.A Moya ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 163 KB

The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 โ€ข C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1