Catalytic oxidation of 1-hexene and cycl
โ
P.J Baricelli; V.J Sรกnchez; A.J Pardey; S.A Moya
๐
Article
๐
2000
๐
Elsevier Science
๐
English
โ 163 KB
The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 โข C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1