The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 • C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1
✦ LIBER ✦
Catalytic oxidation of homoallylalcohols to α-alkoxytetrahydrofurans by a Pd-Nitro complex and molecular oxygen
✍ Scribed by Tom M. Meulemans; Niklaas H. Kiers; Ben L. Feringa; Piet W.N.M.van Leeuwen
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 279 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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