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Catalytic osmylation of allenic compounds. Synthesis of α-hydroxyketo amino acid precursors

✍ Scribed by Katerine David; Cécile Ariente; Alfred Greiner; Jacques Goré; Bernard Cazes


Book ID
103404615
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
187 KB
Volume
37
Category
Article
ISSN
0040-4039

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Copper(salen) complex 1 has been found to catalyse the asymmetric alkylation of enolates derived from a variety of amino acids. There is a clear relationship between the size of the side chain in the substrate and the enantioselectivity of the process, so that the enantioselectivity decreases in the