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Amino acids in catalytic synthesis of α-aminophosphonates

✍ Scribed by E. D. Matveeva; T. A. Podrugina; M. V. Prisyazhnoi; N. S. Zefirov


Book ID
111494670
Publisher
Allerton Press Inc
Year
2007
Tongue
English
Weight
166 KB
Volume
62
Category
Article
ISSN
0027-1314

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Copper(salen) complex 1 has been found to catalyse the asymmetric alkylation of enolates derived from a variety of amino acids. There is a clear relationship between the size of the side chain in the substrate and the enantioselectivity of the process, so that the enantioselectivity decreases in the