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Amino Acids in a Three-Component Synthesis of α-Aminophosphonates Derivatives.

✍ Scribed by E. D. Matveeva; N. S. Zefirov

Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Ute Schmidt; Hans Walter Krause; Günther Oehme; Manfred Michalik; Christine Fisc 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 208 KB 👁 1 views

Chiral ␣-aminophosphonic acid derivatives are efficiently synthesized by asymmetric hydrogenation of the prochiral N-acyl-␣,␤-dehydroaminophosphonates. PROPRAPHOS-Rh-catalysts from readily available (S)-and (R)-Propranolol proved to be suitable in the homogenous reaction affording an enantiomeric ex