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Catalytic hydrogenation using cationic rhodium complexes. 3. The selective hydrogenation of dienes to monoenes

✍ Scribed by Schrock, Richard R.; Osborn, John A.

Book ID
126289344
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
765 KB
Volume
98
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Selective hydrogenation of dienes to mon
Selective hydrogenation of dienes to monoenes catalyzed by (allyl)Pd(II) complexes
✍ Giorgio Strukul; Giovanni Carturan πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 484 KB

diene and 1,7'-octadiene to the corresponding monoenes has been carried out under mild conditions. using different (allyl)Pd(II) den'vatives in NJdimethylacetamide solution. Experiments on the I,3-COD system suggest a mechanism involving the formation of hydrido-Pd(II) species followed by insertion