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Catalysis of dendrimer-bound Pd(II) complex: Selective hydrogenation of conjugated dienes to monoenes

โœ Scribed by Tomoo Mizugaki; Masahiko Ooe; Kohki Ebitani; Kiyotomi Kaneda


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
95 KB
Volume
145
Category
Article
ISSN
1381-1169

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Selective hydrogenation of dienes to mon
โœ Giorgio Strukul; Giovanni Carturan ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 484 KB

diene and 1,7'-octadiene to the corresponding monoenes has been carried out under mild conditions. using different (allyl)Pd(II) den'vatives in NJdimethylacetamide solution. Experiments on the I,3-COD system suggest a mechanism involving the formation of hydrido-Pd(II) species followed by insertion