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Catalytic epoxidation of camphene using methyltrioxorhenium(VII) as catalyst

✍ Scribed by Michel, Typhène; Cokoja, Mirza; Kühn, Fritz E.


Book ID
122811112
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
536 KB
Volume
368-369
Category
Article
ISSN
1381-1169

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Methyltrioxorhenium(VII) as Catalyst for
✍ Prof. Dr. Wolfgang A. Herrmann; Richard W. Fischer; Wolfgang Scherer; Monika U. 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 503 KB

PPh,)(CO),Cp,]+['21 or 3.008(2) 8, in [Mo,(p-StBu),-Further evidence of the high electrophilicity of 2 is the unusual hydride abstraction forced upon BH3 . THE This occurs quickly in dichloromethane at -30 "C and gives the novel unsaturated hydrido complex 4-PF6 in very high yield (CO),Cp]Z + 1131).