Benzimidazolic complexes of methyltrioxorhenium(VII): Synthesis and application in catalytic olefin epoxidation
✍ Scribed by Li, Su; Zhang, Bo; Kühn, Fritz. E.
- Book ID
- 120836694
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 427 KB
- Volume
- 730
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Several Schiff‐base ligands readily form complexes with methyltrioxorhenium(VII) (MTO) by undergoing a hydrogen transfer from a ligand‐bound OH group to a ligand N atom. The resulting complexes are stable at room temperature and can be handled and stored in air without problems. Due to
Dioxomolybdenum(VI) complexes with the general formula [MoO 2 X 2 (N,N)] (X = Cl, OSiPh 3 ) containing a chiral bidentate oxazoline ligand (N,N = 2,2 -bis[(4S)-4-benzyl-2-oxazoline]) have been prepared and characterised by 1 H NMR, IR spectroscopy and thermogravimetric analysis. The bis(chloro) comp
## Abstract Several di‐nitrogen Schiff bases were synthesized through the condensation of 2‐pyridinecarboxaldehyde with primary amines. The Schiff bases as ligands coordinated with methyltrioxorhenium (MTO) smoothly to afford the correspondent complexes which were characterized by IR, ^1^H NMR, ^13