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Catalytic enantioselective synthesis of α -nitroepoxides via aminolytic kinetic resolution

✍ Scribed by Meninno, Sara; Napolitano, Loris; Lattanzi, Alessandra


Book ID
126645435
Publisher
The Royal Society of Chemistry
Year
2015
Tongue
English
Weight
713 KB
Volume
5
Category
Article
ISSN
2044-4753

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## Abstract The transfer hydrogenation of 2‐substituted bicyclic and monocyclic ketimines using HCO~2~H/ Et~3~N as the hydrogen source and TsDPEN‐based Ru(II) and Ir(III) catalysts proceeds with dynamic kinetic resolution to afford the corresponding __cis__‐cycloalkylamines with moderate to excelle