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Enantioselective Synthesis of Vicinal Halohydrins via Dynamic Kinetic Resolution.

โœ Scribed by Abel Ros; Antonio Magriz; Hansjoerg Dietrich; Rosario Fernandez; Elauterio Alvarez; Jose M. Lassaletta


Publisher
John Wiley and Sons
Year
2006
Weight
40 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The transfer hydrogenation of 2โ€substituted bicyclic and monocyclic ketimines using HCO~2~H/ Et~3~N as the hydrogen source and TsDPENโ€based Ru(II) and Ir(III) catalysts proceeds with dynamic kinetic resolution to afford the corresponding __cis__โ€cycloalkylamines with moderate to excelle