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Enantioselective Synthesis of Vicinal Halohydrins via Dynamic Kinetic Resolution

✍ Scribed by Ros, Abel; Magriz, Antonio; Dietrich, Hansjörg; Fernández, Rosario; Alvarez, Eleuterio; Lassaletta, José M.

Book ID
126268073
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
102 KB
Volume
8
Category
Article
ISSN
1523-7060

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Transfer Hydrogenation of α-Branched Ket
Transfer Hydrogenation of α-Branched Ketimines: Enantioselective Synthesis of Cycloalkylamines via Dynamic Kinetic Resolution
✍ Abel Ros; Antonio Magriz; Hansjörg Dietrich; Mark Ford; Rosario Fernández; José  📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 86 KB 👁 1 views

## Abstract The transfer hydrogenation of 2‐substituted bicyclic and monocyclic ketimines using HCO~2~H/ Et~3~N as the hydrogen source and TsDPEN‐based Ru(II) and Ir(III) catalysts proceeds with dynamic kinetic resolution to afford the corresponding __cis__‐cycloalkylamines with moderate to excelle