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Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

✍ Scribed by Jason P Tierney; Alexandre Alexakis; Pierre Mangeney

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 260 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00084-0

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✦ Synopsis

R)-2-Cyclohexen-l-ol and (R)-2-cyclooctene-l-ol have been prepared in very good ee using R,R-homochiral bis-lithium amide bases derived from homochiral C 2 symmetric diamines. (R)-2-Cyclohexen-l-ol has been synthesized in good ee utilising catalytic homochiral bis-lithium amide in the presence of n-butyl lithium. @

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