𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic Enantioselective Aza-Diels-Alder Reactions of Imines-An Approach to Optically Active Nonproteinogenic α-Amino Acids

✍ Scribed by Sulan Yao; Steen Saaby; Rita G. Hazell; Karl Anker Jørgensen


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
382 KB
Volume
6
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Formation of Optically Active Aromatic α
✍ Steen Saaby; Xiangming Fang; Nicholas Gathergood; Karl Anker Jørgensen 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB

Optically active a-amino acids are vital to life as building blocks of peptides, proteins, and many other natural products. Amino acids are also applied extensively as food additives, pharmaceuticals, and agrochemicals. Furthermore, amino acids are widely used in organic synthesis as targets, and as

Catalytic Enantioselective Addition of N
✍ Nagatoshi Nishiwaki; Kristian Rahbek Knudsen; Kurt V. Gothelf; Karl Anker Jørgen 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

The catalytic and asymmetric nitro-Mannich reaction of nitro compounds to α-imino esters catalyzed by chiral bisoxazoline-copper complexes [Eq. (1); Pg = protecting group] gave β-nitro-α-amino esters with excellent diastereo- and enantioselectivities. The reactions can be performed under ambient con

Catalytic Enantioselective Addition of N
✍ Nagatoshi Nishiwaki; Kristian Rahbek Knudsen; Kurt V. Gothelf; Karl Anker Jørgen 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

The development of CÀC bond-forming reactions that create two new stereogenic centers with high diastereo-and enantioselectivity in a single step can open new routes to highly valuable optically active compounds. The catalytic enantioselective addition to imines [1] belongs to this class of importan