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Catalytic Enantioselective [2,3]-Rearrangements of Amine N -Oxides

✍ Scribed by Bao, Hongli; Qi, Xiangbing; Tambar, Uttam K.


Book ID
118141646
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
883 KB
Volume
133
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Tandem Catalytic Al
✍ Arash Soheili; Uttam K. Tambar πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 70 KB πŸ‘ 2 views

## Abstract Allylic carbonates and tertiary amine nucleophiles undergo palladium‐catalyzed formation of ammonium ylides which subsequently rearrange to amino acid derivatives or complex α‐amino ketones with unprecedented levels of diastereocontrol.