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ChemInform Abstract: Tandem Catalytic Allylic Amination and [2,3]-Stevens Rearrangement of Tertiary Amines.

✍ Scribed by Arash Soheili; Uttam K. Tambar

Publisher
John Wiley and Sons
Year
2011
Weight
70 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Allylic carbonates and tertiary amine nucleophiles undergo palladium‐catalyzed formation of ammonium ylides which subsequently rearrange to amino acid derivatives or complex α‐amino ketones with unprecedented levels of diastereocontrol.

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