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ChemInform Abstract: Catalytic Enantioselective [2,3]-Rearrangements of Amine N-Oxides.

✍ Scribed by Hongli Bao; Xiangbing Qi; Uttam K. Tambar


Publisher
John Wiley and Sons
Year
2011
Weight
29 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract Allylic carbonates and tertiary amine nucleophiles undergo palladium‐catalyzed formation of ammonium ylides which subsequently rearrange to amino acid derivatives or complex α‐amino ketones with unprecedented levels of diastereocontrol.