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Catalytic effect on the selectivity of the Diels—Alder reaction

✍ Scribed by V. Branchadell; A. Oliva; J. Bertran

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
368 KB
Volume
97
Category
Article
ISSN
0009-2614

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✦ Synopsis

L'w:~ 1111' MINDO/3 msthod, variation of thr potential barrier for the Dick-Alder rcaclion between I-hydroxybutadicnc .md s~ralsin, cJtA?'zcd b? BF3 and NH:. hJs been studied. An interpretaGon of the experimental facts about the inrrc.tsc of rqIosrlrcIiviry and stereo~ciccti~ it\ for Dick-Alder rextions catalyzed by Lewis acids is &XI.

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